TA Instruments

25% SID 75% PCH R2-0013o

07/07/2022 11:53:14 a. m.

Sample name	25% SID 75% PCH R2
Sample notes	 
Experiment notes	
Operator	
Sample density	1,000 g/cm^3
Results file name	25% SID 75% PCH R2
Run number	13 
Results directory	C:\Ta\Data\Ar1500\Ar1500\DIEGO ROA\Ruby
Experiment was run on	07/07/2022 11:53:14 a. m.

Procedure name	Oscillation procedure
Procedure notes	

Step name	Conditioning Step 1
Step notes	
Perform step	Yes
Initial temperature	25,0 C
Wait for correct temperature	Yes
Do set temperature	Yes
Perform pre-shear	No
Perform equilibration	No
Wait for zero velocity	No
Purge gas only	No

Step name	Temperature sweep step 1
Step notes	
Perform step	Yes
Ramp type	Temperature sweep
Start temperature	25,0 C
End temperature	85,0 C
Temperature increment	5,0 C
Equilibration time	0:01:00 hh:mm:ss
Frequency	0,5000 Hz
Controlled variable	strain 0,010000 
Conditioning time	0:00:03 hh:mm:ss
Sampling time	0:00:03 hh:mm:ss
Sampling type	precision sampling 
Initial osc. stress	0,7958 Pa
Lower torque limit	10,000 micro N.m
Controlled strain sampling number of tries	4 
Controlled strain tolerance	0,50 %
Store all tries as data points	No
Controlled flow variable	torque 0 micro N.m

Step name	Temperature sweep step 2
Step notes	
Perform step	Yes
Ramp type	Temperature sweep
Start temperature	85,0 C
End temperature	25,0 C
Temperature increment	5,0 C
Equilibration time	0:01:00 hh:mm:ss
Frequency	0,5000 Hz
Controlled variable	strain 0,10000 
Conditioning time	0:00:03 hh:mm:ss
Sampling time	0:00:03 hh:mm:ss
Sampling type	precision sampling 
Initial osc. stress	0,7958 Pa
Lower torque limit	10,000 micro N.m
Controlled strain sampling number of tries	4 
Controlled strain tolerance	0,50 %
Store all tries as data points	No
Controlled flow variable	torque 0 micro N.m

Step name	Strain sweep step 1
Step notes	
Perform step	No

Step name	Strain sweep step 2
Step notes	
Perform step	No

Step name	Post-Experiment Step
Step notes	
Perform step	Yes
Do set temperature	Yes
Temperature	25,0 C
Set temperature system idle	No

Geometry name	60 mm 2 steel cone
Geometry notes	Steel cone
Geometry material	Steel
Solvent trap	Yes
Angle	1:59:46 deg:min:sec
Diameter	60,0 mm
Truncation gap	53,00 micro m
Gap offset	0 micro m
Geometry inertia	17,46 micro N.m.s^2
Geometry compliance	1,790E-3 rad/N.m
Gap temperature compensation	0,5 micro m/C
Gap temperature compensation enabled	Yes
Shear rate factor	28,69 
Shear stress factor	17680 1/m^3
Measurement system factor	616,1 1/m^3
Fluid density factor	3,546E-10 m^5
Normal force factor	707,4 1/m^2
Backoff distance	45000 micro m
Approximate sample volume	1,97 ml

Sample compression	none 
Compression distance	1000,0 micro m
Compression velocity	100,0 micro m/s
Fine velocity	1000,0 micro m/s
Coarse velocity	3000,0 micro m/s
Other velocity	3000,0 micro m/s
Current temperature system	Peltier plate
Temperature control	Enabled 
Purge gas only	No
Temperature calibration	Peltier plate - 0,5 micro m/C
	Water bath - 0 micro m/C
	Torsion oven - plate - 0 micro m/C
	Torsion oven - solid sample - 0 micro m/C
	Peltier concentric cylinders - 0 micro m/C
	None - 0 micro m/C
	Stress relaxation - 0 micro m/C
	Current temperature system - 0 micro m/C
Cooling water temperature	5,0 C
Cooling water range	15,0 C
Bearing friction correction	Yes
Bearing friction	1,161 micro N.m/(rad/s)
Bearing offset	0 micro N.m
Temperature system span and offset	Peltier plate - span 1,0000 , offset 0 C
	Water bath - span 1,0000 , offset 0 C
	Torsion oven - plate - span 1,0000 , offset 0 C
	Torsion oven - solid sample - span 1,0000 , offset 0 C
	Peltier concentric cylinders - span 1,0000 , offset 0 C
	None - span 1,0000 , offset 0 C
	Stress relaxation - span 1,0000 , offset 0 C
	Current temperature system - span 1,0000 , offset 0 C
Bearing mapping type	standard 
Number of mapping iterations	1
Instrument type (MType)	AR1500ex
Firmware version	  8.29  27/10/09
Configuration version (CnfVer)	301
Parameter version (PrmVer)	301
PCB Number	*NOT_SET*
IP address	172.23.191.2
Software version	V5.7.2
Windows version	Windows XP 6.2
Instrument inertia	23,24 micro N.m.s^2
Auto increment run number	Yes
Prompt for file name at start of run	Yes
Auto save results file	Yes
Results file storage	Consecutive steps of same type to 1 file 
Temperature tolerance	0,2 C
Temperature duration	0:00:10 hh:mm:ss
Wait for temperature even if OK	Yes
Gap tolerance	4 micro m
Gap duration	0:00:02 hh:mm:ss
Override wait for gap	No
Velocity tolerance	0,1000 rad/s
Zero speed after pre-shear	Leave as is 
Zero normal force before run	No
Zero timer before run	Before pre-shear 
Non-equilibrium minimum velocity	3,000E-4 rad/s
Zero strain at the start of each flow step	Yes
Inertia correction	No
Collect negative shear rate data if stress is positive	Yes
Collect all points	No
Display flow point graph during run	Yes
Store flow point graph with results	Yes
Store images to the results for flow steps	No
Creep zero displacement	Yes
Store images to the results for creep steps	No
Standard creep image store frequency	10 s
Repeated creep image store frequency in repeats	10 
Display oscillation waveform graph during run	Yes
Store oscillation waveform graph with results	Yes
Display strain control tries during run	Yes
Store strain control tries with results	Yes
Store images to the results for oscillation steps	No
Stress relaxation zero displacement	Yes
Store images to the results for stress relaxation steps	No
Flow torque limit	10,00 micro N.m
Flow velocity limit	1,000E-3 rad/s
Oscillation torque limit	5,00 micro N.m
Oscillation displacement limit	1,00E-5 rad
Oscillation raw phase limit	170,0 degrees
Oscillation minimum normal force limit	0 N
Oscillation maximum normal force limit	0 N
Flow velocity tolerance	5,00 %
Oscillation torque tolerance	1,00 %
Oscillation displacement tolerance	5,00 %
Oscillation velocity tolerance	5,00 %
Temperature tolerance	1,0 C

Temperature sweep step 1

ang. frequency	temperature	time	osc. stress	strain	delta	G'	G''	ang. frequency
rad/s	C	s	Pa		degrees	Pa	Pa	rad/s

3,142	25,0	68,938	0,1762	0,46600	106,2	-0,06218	0,2138	3,142
3,142	30,0	157,05	0,1758	0,98605	41,74	0,09090	0,08109	3,142
3,142	35,0	254,80	0,1758	0,99612	40,80	0,09214	0,07954	3,142
3,142	40,0	345,53	0,1759	0,91227	47,65	0,07556	0,08289	3,142
3,142	45,0	446,50	0,1759	0,87395	52,47	0,07064	0,09197	3,142
3,142	50,0	540,23	0,1755	0,79178	58,42	0,1011	0,1644	3,142
3,142	55,0	642,08	0,1754	0,96091	46,92	0,1112	0,1189	3,142
3,142	60,0	745,06	0,1751	0,90990	47,83	0,1479	0,1632	3,142
3,142	65,0	841,47	0,1751	0,76451	44,39	0,2333	0,2284	3,142
3,142	70,0	945,70	0,1765	0,20399	35,30	0,8622	0,6106	3,142
3,142	75,0	1065,0	1,056	9,2786E-3	11,43	111,7	22,58	3,142
3,142	80,0	1180,6	3,159	0,010034	7,407	312,6	40,64	3,142
3,142	85,0	1293,5	2,460	0,010041	6,867	243,6	29,33	3,142

Temperature sweep step 2

ang. frequency	temperature	time	osc. stress	strain	delta	G'	G''	ang. frequency
rad/s	C	s	Pa		degrees	Pa	Pa	rad/s

3,142	85,0	77,719	21,23	0,10055	7,511	209,6	27,64	3,142
3,142	80,0	178,58	17,61	0,099189	8,555	175,8	26,45	3,142
3,142	75,0	299,84	20,58	0,10037	7,403	203,6	26,46	3,142
3,142	70,0	397,39	22,19	0,10043	7,557	219,3	29,09	3,142
3,142	65,0	513,36	23,41	0,10093	7,375	230,4	29,82	3,142
3,142	60,0	634,09	24,82	0,10044	7,407	245,3	31,89	3,142
3,142	55,0	754,80	26,30	0,10037	7,426	260,1	33,90	3,142
3,142	50,0	850,27	27,81	0,10095	7,519	273,4	36,09	3,142
3,142	45,0	951,31	28,71	0,10035	7,613	283,9	37,95	3,142
3,142	40,0	1053,5	30,04	0,10060	7,662	296,4	39,87	3,142
3,142	35,0	1155,8	31,43	0,10041	7,744	310,6	42,23	3,142
3,142	30,0	1259,1	32,79	0,10041	7,842	323,9	44,61	3,142
3,142	25,0	1362,7	34,18	0,10049	8,042	337,3	47,65	3,142

